Product ID:FREON 113
MSDS Date:01/01/1987
FSC:6810
NIIN:00F000143
MSDS Number: BBFYL

Emergency Phone: 201-327-9100

Info Phone: 201-327-9100

Cage: 21994

Telephone: 201-327-5577

Cage: 21994

1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON 113) (SARA

CAS: 76-13-1

RTECS: KJ4000000

Fraction By Weight: 100%

OSHA PEL 1000PPM/1250STEL

ACGIH TLV: 1000PPM/1250STEL9192

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:PRODUCT IS NEITHER CORROSIVE NOR AN
IRRITANT. IT WILL DEFAT & DRY SKIN,POSSIBLY CAUSING DERMATITIS.
VAPOR IS HEAVIER THAN AIR AND CAN CAUSE SUFFOCATION BY REDUCING
OXYGEN AVAILABLE FOR BREATHING.
Explanation of Carcinogenicity:FREON 113 IS NOT LISTED AS A CARCINOGEN
BY IARC, NTP OR OSHA.
Effects of Overexposure:BREATHING HIGH CONCENTRATIONS OF VAPOR MAY
CAUSE LIGHT-HEADEDNESS, GIDDINESS, SHORTNESS OF BREATH, AND MAY
LEAD TO NARCOSIS, CARDIAC IRREGULARITIES, UNCONSCIOUSNESS OR DEATH.
LIQUID CAN CAUSE DEFATTIN G OF TISSUE.
Medical Cond Aggravated by Exposure:SKIN DISEASE - FREON 113 IS A
DEFATTING AGENT AND CAN CAUSE DERMATITIS ON PROLONGED EXPOSURE.
PERSONS WITH PRE-EXISTING SKIN DISORDERS MAY BE MORE SUSCEPTIBLE TO
THE EFFECTS OF THIS AGENT.

First Aid:EYE:FLUSH W/ WATER 15 MIN HOLD LIDS OPEN SEE A DOCTOR.
SKIN:WASH WITH SOAP & WATER. TREAT FOR FROST-BITE IF NEEDED.
INHALED:REMOVE TO FRESH AIR. RESTORE BREATHING, AS NEEDED. DO NOT
GIVE EPINEPHRINE OR SIMILAR DRUGS. INGESTED:DO NOT INDUCE
VOMITING. GET IMMEDIATE MEDICAL CARE. IF IRRITATION PERSISTS,OR
IS SEVERE,SEE A DOCTOR.

Flash Point:NON-FLAMMABLE
Extinguishing Media:PRODUCT IS NON FLAMMABLE. EXTINGUISH FIRE WITH
MEDIA APPROPRIATE FOR SOURCE OF FIRE.
Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA &
FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER
SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE.
Unusual Fire/Explosion Hazard:FIRE OR EXCESSIVE HEAT MAY CAUSE
PRODUCTION OF HAZARDOUS DECOMPOSITION PRODUCTS.

Spill Release Procedures:VENTILATE AREA. DO NOT FLUSH INTO SEWERS.
COLLECT ON ABSORBENT MATERIAL AND TRANSFER TO STEEL DRUMS FOR
RECOVERY OR DISPOSAL.
Neutralizing Agent:NONE

Handling and Storage Precautions:STORE IN A CLEAN, COOL, DRY AND
WELL-VENTILATED AREA OF LOW FIRE RISK. PROTECT CONTAINERS FROM
PHYSICAL DAMAGE AND KEEP CLOSED.
Other Precautions:TANK-CLEANING PERSONNEL SHOULD USE ONLY FORMAL TANK
ENTRY PROCEDURE BASED ON RECOGNIZED SAFETY PRINCIPLES. APPLY ALL
SAFETY PRECAUTIONS TO EMPTY CONTAINERS AS THEY MAY CONTAIN PRODUCT
RESIDUES/VAPORS.

Respiratory Protection:RESPIRATOR WILL NOT NORMALLY BE NECESSARY. USE
NIOSH/MSHA APPROVED AIR SUPPLIED RESPIRATOR OR SELF CONTAINED
BREATHING APPARATUS IF EXPOSURE IS ABOVE THE TLV/PEL. SEE 29 CFR
1910.134 FOR REGULATIONS PERTAINING TO RESPIRATOR USE.
Ventilation:PROVIDE LOCAL EXHAUST AT FILLING ZONES AND OTHER OPERATING
SPACES WHERE LEAKAGE IS PROBABLE. MECHANICAL FOR OTHER.
Protective Gloves:LINED BUTYL RUBBER, PVA OR NEOPRENE
Eye Protection:SAFETY GLASSES OR SPLASH GOGGLES
Other Protective Equipment:USE IMPERVIOUS CLOTHING IF THERE IS DANGER
OF REPEATED OR PROLONGED CONTACT WITH LIQUID.
Work Hygienic Practices:USE GOOD CHEMICAL HYGIENE PRACTICE. AVOID
CONTACT. REMOVE AND WASH CLOTHING PROMPTLY UPON CONTAMINATION.
Supplemental Safety and Health
HONEYWELL FEDERAL SYSTEMS SUPPLIED THIS MATERIAL (NO NSN) AND AN MSDS
FROM TEXWIPE COMPANY. MSDS WAS OSHA FORM 20 AND OF POOR QUALITY
EVEN FOR A FORM 20. CONTRACT AT DGSC WAS DLA400-88-A-B5360133.

HCC:N1
Boiling Pt:B.P. Text:117F,47C
Vapor Pres:334 MM
Vapor Density:2.9
Spec Gravity:1.57
Evaporation Rate & Reference:0.3 CARBON TETRACHLORIDE
Solubility in Water:0.02%
Appearance and Odor:CLEAR, COLORLESS LIQUID, SLIGHTLY ETHEREAL ODOR
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
ALKALI OR ALKALINE EARTH METALS AND POWDERED REACTIVE METALS SUCH AS
ALUMINUM AND ZINC
Stability Condition to Avoid:HIGH TEMPERATURES, AND OPEN FLAMES
Hazardous Decomposition Products:DECOMPOSED BY HIGH TEMPERATURES (OPEN
FLAMES, GLOWING METAL SURFACES, ETC.) FORMING HYDROCHLORIC AND
HYDROFLUORIC ACIDS.

Waste Disposal Methods:DISPOSE I/A/W ALL FEDERAL, STATE AND LOCAL
REGULATIONS. MANUFACTURER SUGGESTS THAT RECLAIMATYION BY
DISTILLATION OR DISPOSAL BY A PERMITTED FACILITY.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.